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• W2025781934 abstract "The anomalous contraction that cerium undergoes when it is the A component in AB2 Laves phase compounds is used to estimate its metallic radius when it is joined to a given B component. In each case, isostructural compounds of trivalent (rare earths) and tetravalent (zirconium, hafnium and thorium) A elements with the same B element are taken as the reference system. The trivalent metallic radius (r3 = 1.846 Å) of cerium proposed by Gschneidner and Smoluchowski was confirmed, but a tetravalent metallic radius (r4 = 1.688 Å) of cerium which exceeds their value by 1% was obtained. The presence of A-B contacts is related to the intermediate valency behaviour, and the valency calculated for each compound is compared with other physical properties. A distinction between localized conduction band hybridization and interconfigurational fluctuation is proposed." @default.
• W2025781934 created "2016-06-24" @default.
• W2025781934 creator A5039678659 @default.
• W2025781934 date "1982-03-01" @default.
• W2025781934 modified "2023-09-23" @default.
• W2025781934 title "The cerium metallic radius in AB2 (C15) laves compounds (A ≡ Ce)" @default.
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• W2025781934 doi "https://doi.org/10.1016/0022-5088(82)90122-9" @default.
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