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• W2025801572 abstract "The rate constant for the reaction Cl+D2 was measured over the temperature range 200–500 K, using the flash photolysis-resonance fluorescence technique. These data, together with previous measurements for Cl+H2, are compared with the isotope effect measured by Persky and Klein in a static bulb. Over the range 295–500 K, our data are in excellent agreement with their results. At lower temperatures, the Cl+D2 rate constant displays an anomalous non-Arrhenius curvature. A mechanism involving the reaction of Cl atoms with vibrationally excited D2 is proposed to explain this effect." @default.
• W2025801572 created "2016-06-24" @default.
• W2025801572 creator A5040187424 @default.
• W2025801572 creator A5041061619 @default.
• W2025801572 date "1983-08-01" @default.
• W2025801572 modified "2023-10-18" @default.
• W2025801572 title "Kinetics of the Cl–H₂ system. III. The deuterium isotope effect in Cl+H₂" @default.
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• W2025801572 doi "https://doi.org/10.1063/1.445932" @default.
• W2025801572 hasPublicationYear "1983" @default.
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