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- W2025804611 abstract "Jet-cooled laser-induced fluorescence spectra of the B ← X electronic transition of 1-methylvinoxy and of a cis/trans mixture of 2-methylvinoxy are presented. We observe some 50 vibronic bands in the spectrum of 1-methylvinoxy. The complexity is due to a change in the preferred methyl rotor orientation on electronic excitation. The B-state barrier to internal rotation is approximately 750 cm-1. The B-state fluorescence lifetimes decrease from about 130 ns near the origin to 26 ns for internal energy of 2700 cm-1. We observe some 22 vibronic bands in the spectrum of the cis/trans mixture of 2-methylvinoxy. The B-state fluorescence lifetimes decrease gradually from about 190 ns near the origin to 140 ns for internal energy of 1170 cm-1 and then very sharply at higher energy. The new spectra serve as fingerprints for identification of specific methylvinoxy isomers as products of chemical reactions of O(3P) with alkenes, as recently observed by Bersohn and co-workers." @default.
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- W2025804611 date "1998-03-01" @default.
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- W2025804611 title "B̃ ← X̃ Vibronic Spectra and B̃-State Fluorescence Lifetimes of Methylvinoxy Isomers" @default.
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- W2025804611 doi "https://doi.org/10.1021/jp980451u" @default.
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