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- W2025810135 abstract "Reaction of tris(2-pyridyl)phosphine with chlorine in dichloromethane or acetonitrile gave chlorotris(2-pyridyl)phosphonium chloride which afforded a coupling product, 2,2′-bipyridyl, by treating with dilute HCl. Treatment of tris(2-pyridyl)phosphine or tris(2-pyridyl)phosphine oxide with chlorine or bromine in methanol gave unusual 5-halo-2,2′-bipyridyl as a major coupling product. This is undoubedly an electrophilic substitution on a pyridyl ring in the pentacovalent phosphorane." @default.
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- W2025810135 date "1995-06-01" @default.
- W2025810135 modified "2023-10-16" @default.
- W2025810135 title "Unusual formation of 5-halo-2,2′-bipyridyls by treatment of tris(2-pyridyl)phosphine derivatives with halogens" @default.
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- W2025810135 doi "https://doi.org/10.1016/0040-4039(95)00719-s" @default.
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