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- W2025819825 abstract "A novel aliphatic polyester containing a malonate group in the main chain was prepared by one-pot reaction of malonyl dichloride with ethylene glycol in the presence of triethylamine. The NMR, IR, and UV−vis studies revealed that the polymer partially underwent intra- and intermolecular Knoevenagel type self-condensation in solution and solid states, respectively, leading to formation of a certain conjugated structure in the polymer chain. The polymer exhibited a very weak, but clear, absorption around 363 nm as well as an absorption at 322 nm due to carbonyl n−π* transition. Furthermore, the polymer exhibited blue/greenish-blue photoluminescence due to ESIPT when excited at wavelengths longer than 350 nm. This polymer is the first example of a colored and photoluminescent aliphatic polyester." @default.
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- W2025819825 date "2004-02-27" @default.
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- W2025819825 title "Colored and Luminous Aliphatic Polyester via One-Pot Intra- and Intermolecular Knoevenagel Reactions" @default.
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- W2025819825 doi "https://doi.org/10.1021/ma035679g" @default.
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