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- W2025823786 abstract "A systematic synthesis of the N-methyl-1-deoxynojirimycin-containing oligosaccharides related to the Lewis x, Lewis a, sialyl-Lewis x and sialyl-Lewis a antigens has been achieved. The couplings of the suitably protected 1-deoxynojirimycin derivative 10 with methyl-1-thioglycosides (glycosyl donors) of L-fucose (11), D-galactose (15) and alpha-sialyl-(2-->3)-D-galactose (27) were carried out by using dimethyl(methylthio)sulfonium triflate (DMTST) or N-iodosuccinimide/trifluoromethanesulfonic acid (NIS/TfOH) as the glycosyl promoter. The resulting di- and tri-saccharides were each converted, by further cross glycosylations with 11, 15 or 27, to the desired tri- and tetra-saccharides 3-6 that inhibit the recognition between sialyl-Lewis x and selectins, a family of leukocyte cell adhesion molecules." @default.
- W2025823786 created "2016-06-24" @default.
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- W2025823786 date "1994-11-01" @default.
- W2025823786 modified "2023-09-25" @default.
- W2025823786 title "Systematic synthesis of N-methyl-1-deoxynojirimycin-containing, Lex, Lea, sialyl-Lex and sialyl-Lea epitopes recognized by selectins" @default.
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- W2025823786 doi "https://doi.org/10.1016/s0968-0896(00)82080-5" @default.
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