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• W2025839568 abstract "Interruption of the hyperfine interaction during electron spin-exchange collisions shifts the hydrogen-atom ground-state $ensuremath{Delta}{m}_{F}=0$ hyperfine transition frequency in proportion to the spin-exchange collision rate and to the average time ${T}_{D}$ during which the exchange interaction interrupts the hyperfine interaction. Measurements of the thermal average ${T}_{D}$ for hydrogen-hydrogen collisions at 308 ifmmode^circelsetextdegreefi{}K in an atomic hydrogen maser confirm the predictions of a semiclassical theory and a numerical estimate using straight-line collision trajectories. Measurements of much longer ${T}_{D}$ for hydrogen-atom collisions with ${mathrm{O}}_{2}$, NO, and N${mathrm{O}}_{2}$ molecules are consistent with the formation of long-lived intermediate complexes during some collisions." @default.
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• W2025839568 date "1975-10-01" @default.
• W2025839568 modified "2023-10-16" @default.
• W2025839568 title "Duration of hydrogen-atom spin-exchange collisions" @default.
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• W2025839568 doi "https://doi.org/10.1103/physreva.12.1305" @default.
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