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- W2025846702 abstract "Abstract A cubic spinel conductor CuV 2 S 4 , containing the corner-sharing tetrahedral lattice of V, was investigated. Above a structural transition at 90 K, the 51 V nuclear spin-relaxation rate 1/ T 1 is comparatively large in magnitude and tends to saturate at higher temperatures, indicating that the V lattice behaves as a nearly antiferromagnetic metal. By substituting nonmagnetic Sn for V, the susceptibility turns to be of Curie–Weiss type and 51 V -1/T 1 temperature-independent, suggesting recovery of hidden spins as a result of a partial release of the frustration. These results lead to the conclusion that CuV 2 S 4 is an itinerant-electron frustrated system as YMn 2 . The CDW transition of CuV 2 S 4 accompanied by a tetragonal distortion which may be understood as a result of lowering of interaction dimensionality inherent to the corner-sharing tetrahedral lattice." @default.
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- W2025846702 date "2004-03-01" @default.
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- W2025846702 title "Geometric frustration in CuV2S4" @default.
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- W2025846702 doi "https://doi.org/10.1016/j.ssc.2003.08.035" @default.
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