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- W2025864650 abstract "A model, based on Helmholtz energy, describing the thermodynamics of NaCl solutions in the near-critical region of water has been developed and tested as a function of temperature (350−402 °C), pressure (18−41 MPa), and solute concentration (0−5 m) using literature heat of dilution (ΔdilH) data. This model is an extension of one developed by Anderko and Pitzer (Geochim. Cosmochim. Acta 1993, 57, 1657−1680) as modified by Oscarson et al. (Ind. Eng. Chem. Res. 2001, 40, 2176−2182). The present model includes terms for NaCl dissociation and ion−ion interactions. Density and ΔdilH values predicted using the model agree well with literature values over the temperature, pressure, and solute concentration ranges of the study. Apparent log K‘, ΔrH, ΔrS, and ΔrCpvalues change significantly with the solute concentration, temperature, and solution density. The model was used to determine speciation in aqueous NaCl solutions under the conditions of the study." @default.
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- W2025864650 date "2004-11-01" @default.
- W2025864650 modified "2023-09-25" @default.
- W2025864650 title "A Model Incorporating Ion Dissociation, Solute Concentration, and Solution Density Effects To Describe the Thermodynamics of Aqueous Sodium Chloride Solutions in the Critical Region of Water" @default.
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- W2025864650 doi "https://doi.org/10.1021/ie040112p" @default.
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