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• W2025879295 abstract "Carbon-13 relaxation times, T1, have been measured for ten cobalt(III)–cyclohexanedione dioxime complexes: CH3CH2Co(Niox)2-p-R-pyridine [RH, N(CH3)2, CH3, C2H5, C(CH3)3, Cl, Br, CN and COCH3] and CH3CH2Co(Niox)2-3-N-methylimidazole. The values obtained have been rationalized by making assumptions on the length of the metal—hetrocyclic nitrogen bond. The internal rotation around the axial CoN (heterocyclic) bond is faster for the 3-N-methylimidazole ligand than for the pyridine ligands. Correlations of the T1 values with the σ-donor and π-acceptor character of the pyridine ligands were attempted. The interpretation of the results suggests the existence of π-back-bonding from the metal to the N-1 pyridine nitrogen atom, in agreement with the results of other workers. This conclusion, however, was not supported by the use of the para-C chemical shift as a criterion for back-bonding in pyridine–transition metal complexes." @default.
• W2025879295 created "2016-06-24" @default.
• W2025879295 creator A5045475610 @default.
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• W2025879295 date "1982-09-01" @default.
• W2025879295 modified "2023-09-26" @default.
• W2025879295 title "13C relaxation times,T1, in six-coordinate cobalt(III) complexes: Study of the axial CoN (heterocyclic) bond" @default.
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• W2025879295 doi "https://doi.org/10.1002/mrc.1270200103" @default.
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