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- W2025882504 abstract "To elucidate effects of electrostatic interactions due to the surface charges on structures and phase stability of cubic phases of lipids, the mixture membranes of monoolein (MO) and oleic acid (OA) (OA/MO membrane) have been investigated by small-angle X-ray scattering method. As increasing OA concentration in the OA/MO membrane, a phase transition from Q224 to Q229 phase occurred, and above 1.0 mol% OA, OA/MO membranes were in the Q229 phase. However, when NaCl concentration in the bulk phase is large, the Q224 phase is more stable than the Q229 phase in the OA/MO membranes containing high concentrations of OA. These results indicate that the electrostatic repulsion between the headgroups of these membranes makes the Q229 phase more stable than the Q224 phase. We have also found that lowering pH induces a phase transition from Q229 to Q224, and at lower pH a phase transition from Q224 to HII. These results are discussed in terms of the spontaneous curvature of the monolayer membrane and a lipid packing parameter of the membrane." @default.
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- W2025882504 date "1999-11-01" @default.
- W2025882504 modified "2023-09-29" @default.
- W2025882504 title "Effects of electrostatic interaction on the phase stability and structures of cubic phases of monoolein/oleic acid mixture membranes" @default.
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- W2025882504 doi "https://doi.org/10.1016/s0005-2736(99)00156-x" @default.
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