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• W2025891445 abstract "The elastic deformation of a soft solid induced by capillary forces crucially relies on the excess stress inside the solid-liquid interface. While for a liquid-liquid interface this surface stress is strictly identical to the surface free energy, the thermodynamic Shuttleworth equation implies that this is no longer the case when one of the phases is elastic. Here we develop a microscopic model that incorporates enthalpic interactions and entropic elasticity, based on which we explicitly compute the surface stress and surface free energy. It is found that the compressibility of the interfacial region, through the Poisson ratio near the interface, determines the difference between surface stress and surface energy. We highlight the consequence of this finding by comparing with recent experiments and simulations on partially wetted soft substrates." @default.
• W2025891445 created "2016-06-24" @default.
• W2025891445 creator A5043831567 @default.
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• W2025891445 date "2014-04-28" @default.
• W2025891445 modified "2023-10-03" @default.
• W2025891445 title "Capillarity of soft amorphous solids: A microscopic model for surface stress" @default.
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• W2025891445 doi "https://doi.org/10.1103/physreve.89.042408" @default.
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• W2025891445 hasPublicationYear "2014" @default.
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