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• W2025908962 abstract "Dissolved and particulate fatty acids have been analyzed by gas chromatography and gas chromatography/mass spectrometry in microlayer and subsurface water samples from the open Mediterranean sea. Structural elucidation of these compounds was performed before and after derivatization with dimethyldisulfide (DMDS) by GC/MS analyses of the fatty acid methyl esters (FAMEs) and their methylthio derivatives to locate the double bond of the monounsaturated FAMEs. Several hundred data were analyzed using a statistical approach. A multivariate method, CFA (Correspondence Factorial Analysis), and a non-parametric procedure. HCC (Hierarchical Clustering Classification), were used together to investigate the planktonic and microbiological sources in order to further characterize our samples. These statistical treatments allowed us to distinguish different inputs in the dissolved and particulate material: esters in the particulate material showed a major phytoplanktonic input dominated by the presence of diatoms except in one sample where zooplankton prevailed. Higher amounts of C15 and C17 branched and monounsaturated FAMEs indicated a stronger bacterial fingerprint for the dissolved FAMEs. C16:1ω10, previously unreported in seawater displayed a similar statistical behavior as other bacterial FAMEs suggesting a microbial origin of this compound. Dissolved FAMEs extracted from acidified seawater and particulate esterified FAMEs showed similar composition." @default.
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• W2025908962 date "1988-01-01" @default.
• W2025908962 modified "2023-10-14" @default.
• W2025908962 title "Characterization of seawater samples using chemometric methods applied to biomarker fatty acids" @default.
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• W2025908962 doi "https://doi.org/10.1016/0146-6380(88)90265-3" @default.
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