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- W2025920106 abstract "Time-resolved infrared spectroscopy was used to study the photoisomerization of N-Methylthioacetamide (NMTAA) in D2O in both the cis-->trans and the trans-->cis direction upon selective excitation of the n-pi (S1) and pi-pi (S2) electronic transitions. While isomerization and the return to the ground state takes place on two distinct time scales (<or=8 ps, approximately 250 ps) upon pi-pi excitation of both cis- and trans-NMTAA in D2O, ground state recovery is only observed on the slower time scale upon n-pi excitation. The quantum efficiency for trans-->cis isomerization is 30-40%, independent of the electronic state excited, while the cis-->trans isomerization proceeds with a 60-70% quantum efficiency. These results support a mechanism by which isomerization takes place via one common intermediate state independent of electronic excitation energy and initial conformation." @default.
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- W2025920106 date "2006-09-20" @default.
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- W2025920106 title "Time-Resolved IR Spectroscopy of <i>N</i>-Methylthioacetamide: Trans → Cis Isomerization upon n−π<sup>*</sup> and π−π<sup>*</sup> Excitation and Cis → Trans Photoreaction" @default.
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- W2025920106 doi "https://doi.org/10.1021/jp062856h" @default.
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