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• W2025948369 startingPage "2069" @default.
• W2025948369 abstract "Abstract Homo‐ and bishomododecahedral cage molecules with one and two OCO (OCH 2 ) linkers installed into the parent pentagonal framework and featuring diverse functionalization patterns have been made available from pagodane precursors via highly expeditious synthetic sequences. The enforced geometrical changes with respect to molecular curvature, olefinic pyramidalization, transannular π,π‐distance as well as to the chemical reactivity particularly of the unsaturated homododecahedranes are generally in good agreement with expectations based on calculations (MM2). In the appreciably pyramidalized monohomododecahedradiene skeleton 40 the non‐parallel π‐bonds are ca. 2.9 (3.1) Å [Φ = ca. 20 (32)°, MM2], in the bishomododecahedradiene skeleton 55 the perfectly syn ‐periplanar π‐bonds 2.81 Å apart (Φ = 18.2°, X‐ray crystal structure)." @default.
• W2025948369 created "2016-06-24" @default.
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• W2025948369 date "1997-10-01" @default.
• W2025948369 modified "2023-10-17" @default.
• W2025948369 title "From Pagodanes to Homologous, Non‐Pentagonal Dodecahedranes" @default.
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• W2025948369 doi "https://doi.org/10.1002/jlac.199719971010" @default.
• W2025948369 hasPublicationYear "1997" @default.
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