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- W2025949351 abstract "Abstract The spin-Hamiltonian electron-nuclear hyperfine interaction parameters A and B of 53 Cr 3+ in trigonally distorted sites of hydrated crystals are analyzed in terms of a model which includes the effect of crystal vibration and static distortion, in addition to the Fermi contact term. The model is based on the vibrational and static parts of A and B being proportional to the vibrational and static parts of the zero-field splitting parameter D , which have been found previously. The analysis allows the temperature dependence of the hyperfine parameters to be predicted when the measured values at 4.2 K are used as a starting point. Room-temperature measurements of A and B in guanidinium aluminum selenate hexahydrate (GAlSeH) gives agreement between the predicted and measured values, to the accuracy of measurement." @default.
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- W2025949351 date "1977-08-01" @default.
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- W2025949351 title "Analysis of the 53Cr3+ spin-hamiltonian hyperfine interaction parameters A and B in hydrated crystals" @default.
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- W2025949351 doi "https://doi.org/10.1016/0022-2364(77)90073-7" @default.
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