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- W2025960054 abstract "The nucleophilic ring opening of trans-aziridine-2,3-dicarboxylate 1 and substituted N-acyl-, N-(methoxycarbonyl)-, and N-(methanesulfonyl)aziridine-2,3-dicarboxylates 2−4 allows an easy synthetic approach to β-hydroxy, β-amino, β-(alkylthio), and β-halogenoaspartates 5−8; in this respect, compounds 2−4 display higher reactivities. The erythro stereochemistry of the synthesized aspartates and the SN2-like mechanism of the nucleophilic attack were unambiguously identified by the (2R,3S) X-ray absolute configuration determination of enantiomerically pure β-amino derivative 9, obtained from (2R,3R)-4, and by its chemical correlation with meso α,β-bis[N-(methanesulfonyl)amino]succinate (10)." @default.
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- W2025960054 date "1997-12-01" @default.
- W2025960054 modified "2023-10-06" @default.
- W2025960054 title "Stereoselective Synthesis of <i>Erythro</i> β-Substituted Aspartates" @default.
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- W2025960054 doi "https://doi.org/10.1021/jo971285+" @default.
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