FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2025971585> ?p ?o ?g. }

• W2025971585 endingPage "7154" @default.
• W2025971585 startingPage "7147" @default.
• W2025971585 abstract "Solvent-sensitive probes have wide application in the study and characterization of interfacial systems. This work presents some new, more hydrophobic versions of the solvatochromic π* indicators of solvent dipolarity−polarizability. The new dyes form a homologous series of N,N-dialkyl-p-nitroanilines. The indicators are designed to act as improved probes of micelles and lipid bilayers in polar and aqueous solutions. UV−vis studies of the N,N-dipentyl- and N,N-dihexyl-p-nitroanilines show the two indicators to be strongly solvatochromic; values of −s estimated from two-point correlation are 3.081and 3.110, respectively. UV−vis spectra of N,N-dipentyl- and N,N-dihexyl-p-nitroanilines obtained at variable indicator concentration in cyclohexane and dimethyl sulfoxide, within the 10-5 M concentration range, display no concentration-dependent spectral shifting and no evidence of indicator aggregation in accordance with Beer's law. Studies of the indicator series in aqueous solutions of varying concentration of the anionic surfactant sodium dodecyl sulfate (SDS) suggest that N,N-dipropyl-p-nitroaniline probes micelles of SDS more deeply than the commonly used N,N-dimethyl- and N,N-diethyl-p-nitroanilines. Of the three indicators in the series, N,N-dimethyl-, N,N-diethyl-, and N,N-dipropyl-p-nitroaniline, the dipropyl species is most responsive to the critical micelle concentration of SDS. The longer chain dyes N,N-dibutyl-, N,N-dipentyl-, and N,N-dihexyl-p-nitroaniline are more effective probes of larger micelles of the nonionic surfactant Triton X-114. UV−vis studies of N,N-dihexyl-p-nitroaniline in micellar solutions of Triton X-114 and model systems suggest that the longest chain indicator probes the outer polyoxyethylene portion of the Triton X-114 micelle." @default.
• W2025971585 created "2016-06-24" @default.
• W2025971585 creator A5034107486 @default.
• W2025971585 creator A5050796573 @default.
• W2025971585 creator A5057821921 @default.
• W2025971585 creator A5065511624 @default.
• W2025971585 date "1998-11-19" @default.
• W2025971585 modified "2023-10-11" @default.
• W2025971585 title "New Hydrophobic π* Indicators. Solvatochromic Properties and Interactions in Micellar Solutions" @default.
• W2025971585 cites W1489601464 @default.
• W2025971585 cites W1545435796 @default.
• W2025971585 cites W1963925740 @default.
• W2025971585 cites W1968746190 @default.
• W2025971585 cites W1968841999 @default.
• W2025971585 cites W1972739388 @default.
• W2025971585 cites W1973004672 @default.
• W2025971585 cites W1975576432 @default.
• W2025971585 cites W1983992843 @default.
• W2025971585 cites W1990767050 @default.
• W2025971585 cites W1993577167 @default.
• W2025971585 cites W1997641425 @default.
• W2025971585 cites W1999041059 @default.
• W2025971585 cites W2002302107 @default.
• W2025971585 cites W2002680703 @default.
• W2025971585 cites W2004478983 @default.
• W2025971585 cites W2005148658 @default.
• W2025971585 cites W2013840970 @default.
• W2025971585 cites W2014468409 @default.
• W2025971585 cites W2017744447 @default.
• W2025971585 cites W2020574673 @default.
• W2025971585 cites W2023643670 @default.
• W2025971585 cites W2024009416 @default.
• W2025971585 cites W2026768842 @default.
• W2025971585 cites W2028655299 @default.
• W2025971585 cites W2028727748 @default.
• W2025971585 cites W2029807337 @default.
• W2025971585 cites W2049264377 @default.
• W2025971585 cites W2055183264 @default.
• W2025971585 cites W2055914734 @default.
• W2025971585 cites W2069610606 @default.
• W2025971585 cites W2070628047 @default.
• W2025971585 cites W2070800417 @default.
• W2025971585 cites W2072278204 @default.
• W2025971585 cites W2076730421 @default.
• W2025971585 cites W2076866326 @default.
• W2025971585 cites W2081377598 @default.
• W2025971585 cites W2082912596 @default.
• W2025971585 cites W2085964737 @default.
• W2025971585 cites W2089049959 @default.
• W2025971585 cites W2092015897 @default.
• W2025971585 cites W2095277175 @default.
• W2025971585 cites W2132709044 @default.
• W2025971585 cites W2134067178 @default.
• W2025971585 doi "https://doi.org/10.1021/la980787v" @default.
• W2025971585 hasPublicationYear "1998" @default.
• W2025971585 type Work @default.
• W2025971585 sameAs 2025971585 @default.
• W2025971585 citedByCount "19" @default.
• W2025971585 countsByYear W20259715852012 @default.
• W2025971585 countsByYear W20259715852020 @default.
• W2025971585 crossrefType "journal-article" @default.
• W2025971585 hasAuthorship W2025971585A5034107486 @default.
• W2025971585 hasAuthorship W2025971585A5050796573 @default.
• W2025971585 hasAuthorship W2025971585A5057821921 @default.
• W2025971585 hasAuthorship W2025971585A5065511624 @default.
• W2025971585 hasConcept C11268172 @default.
• W2025971585 hasConcept C178790620 @default.
• W2025971585 hasConcept C184651966 @default.
• W2025971585 hasConcept C185592680 @default.
• W2025971585 hasConcept C2776482079 @default.
• W2025971585 hasConcept C2778237882 @default.
• W2025971585 hasConcept C2778452553 @default.
• W2025971585 hasConcept C2778913249 @default.
• W2025971585 hasConcept C2780471494 @default.
• W2025971585 hasConcept C55493867 @default.
• W2025971585 hasConcept C58226133 @default.
• W2025971585 hasConcept C67218372 @default.
• W2025971585 hasConceptScore W2025971585C11268172 @default.
• W2025971585 hasConceptScore W2025971585C178790620 @default.
• W2025971585 hasConceptScore W2025971585C184651966 @default.
• W2025971585 hasConceptScore W2025971585C185592680 @default.
• W2025971585 hasConceptScore W2025971585C2776482079 @default.
• W2025971585 hasConceptScore W2025971585C2778237882 @default.
• W2025971585 hasConceptScore W2025971585C2778452553 @default.
• W2025971585 hasConceptScore W2025971585C2778913249 @default.
• W2025971585 hasConceptScore W2025971585C2780471494 @default.
• W2025971585 hasConceptScore W2025971585C55493867 @default.
• W2025971585 hasConceptScore W2025971585C58226133 @default.
• W2025971585 hasConceptScore W2025971585C67218372 @default.
• W2025971585 hasIssue "25" @default.
• W2025971585 hasLocation W20259715851 @default.
• W2025971585 hasOpenAccess W2025971585 @default.
• W2025971585 hasPrimaryLocation W20259715851 @default.
• W2025971585 hasRelatedWork W1534794449 @default.
• W2025971585 hasRelatedWork W1975369176 @default.
• W2025971585 hasRelatedWork W1983656507 @default.
• W2025971585 hasRelatedWork W2022436773 @default.
• W2025971585 hasRelatedWork W2050258677 @default.

• next