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- W2025973667 abstract "Using the diaphram cell and gel sectioning techniques, the existence of significant isotope-mass effects in self-diffusion has been confirmed for the organic liquids benzene and cyclohexane in the temperature range 280–313 K. The former shows a small but significant mass effect of the expected sense [D(lighter isotope) > D(heavier isotope)] which is constant and independent of temperature. The latter liquid shows no mass effect at the lower end of the temperature range but a reversed mass effect at higher temperatures. This surprising distinction is not predicted by any existing empirical or theoretical model for diffusion in the liquid state." @default.
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- W2025973667 date "1980-01-01" @default.
- W2025973667 modified "2023-10-17" @default.
- W2025973667 title "Diffusion in organic liquids. Part 2.—Isotope-mass effects in self-diffusion in benzene and cyclohexane" @default.
- W2025973667 doi "https://doi.org/10.1039/f19807601030" @default.
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