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- W2025978044 abstract "The characteristics of Tiron (1,2-dihydroxybenzene-3,5-disulfonic acid and its sodium salt) solution as an eluent for anions in ion-exchange chromatography was investigated with conductivity and UV absorbance detectors. Tiron (acid and sodium salt) has such a strong affinity for the anion exchanger that the concentration in the eluent can be made lower than that of benzene carboxylates, such as phthalate, which have been used similarly. Tiron acid exhibited an unusual effect which increased the sensitivity with a conductivity detector. The water dip was not observed, and a big ghost peak appeared near the sulfate peak. Tiron salt did not produce a ghost peak, and was better for highly sensitive detection in indirect photometric chromatography than phthalate, because of a better balance between UV absorptivity and elution ability. Because Tiron forms stable chelates with many metal ions, pretreatment with a cation-exchange resin is necessary for real samples such as tap water." @default.
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- W2025978044 date "1988-01-01" @default.
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- W2025978044 title "Ion-exchange chromatography of anions with tiron as eluent" @default.
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- W2025978044 doi "https://doi.org/10.1016/s0003-2670(00)80850-8" @default.
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