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- W2026002335 abstract "An empirical equation of state for supercritical fluids has been derived based on the power laws and the thermodynamic equation of state P = (ϖS/ϖV)TT − (ϖU/ϖV)T. The equation of state derived in this work is given by p=P∗(T)−ak(T)Xe−x−bk(T)[X+ck(T)]4X where P∗(T), ak(T), bk(T), and ck(T) are functions of temperature and suffix k means a state of fluid such as k = l for the liquid-like region V < Vc and k = g for the gas-like region V > Vc in the supercritical region T > Tc. The quantity X is defined by X = (V − Vc)/V where Vc is the critical volume and Tc is the critical temperature. The equation of state for five fluids, neon, hydrogen, deuterium, carbon monoxide, and helium is given by a modified form P=P∗(T)−{ak(T)+bk(T)[X+ck(T)]4}Xe−x Comparisons between the PV isotherms for methane calculated by the Benedict-Webb-Rubin (B-W-R), the Beattie-Bridgeman (B-B) equations of state and the equation of state in this work have been done and it is found that the present equation of state gives a good agreement with the data in the same order of accuracy as the B-W-R and B-B equations of state." @default.
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- W2026002335 date "1995-03-01" @default.
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- W2026002335 title "Empirical equation of state for supercritical fluids" @default.
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- W2026002335 doi "https://doi.org/10.1016/0896-8446(95)90048-9" @default.
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