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• W2026008087 abstract "Single crystal X-ray diffraction of Eu(SC36H49)2 has revealed a first order phase transition at a temperature of 119 K, that involves a reduction of the specific volume by 1 %. The transition corresponds to a doubling of the unit cell, as it is the result from reorientations of isopropyl groups that appear at peripheral sites of the organic ligands. It is argued that a denser packing is achieved at the expense of a less favourable conformation of one of the two crystallographically-independent complexes in the low-temperature phase. The Bond-Valence method is used to show that interactions of equal strengths are present between europium and both sulphur atoms and both coordinating phenyl rings." @default.
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• W2026008087 date "2007-06-01" @default.
• W2026008087 modified "2023-09-27" @default.
• W2026008087 title "Phase Transition and Crystal Structure of the Monomeric Europium(II) Thiolate Eu(SC36H49)2" @default.
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• W2026008087 doi "https://doi.org/10.1002/zaac.200600398" @default.
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