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- W2026022185 abstract "Abstract Single‐component molecular conductors [M(tmstfdt) 2 ] (M = Ni, Au; tmstfdt = trimethylenediselenadithiafulvalenedithiolate) substituted with Se atoms are prepared and found to be isostructural with [M(tmdt) 2 ] (M = Ni, Au; tmdt = trimethylenetetrathiafulvalenedithiolate). Measurements of the electrical conductivity and magnetic susceptibility of [Ni(tmstfdt) 2 ] show that it has essentially metallic properties down to low temperatures. The resistivity measurements of [Au(tmstfdt) 2 ] suggest it undergoes a metal‐insulator phase transition at around 100 K. Magnetic susceptibility and ESR measurements of [Au(tmstfdt) 2 ] indicate that it undergoes a magnetic transition at around 5 K, which is much lower than theantiferromagnetic (AF) phase‐transition temperature of [Au(tmdt) 2 ] (110 K). (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)" @default.
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- W2026022185 date "2009-04-01" @default.
- W2026022185 modified "2023-10-03" @default.
- W2026022185 title "Structures and Physical Properties of Highly Conducting Single‐Component Molecular Conductors Containing Se Atoms" @default.
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- W2026022185 doi "https://doi.org/10.1002/ejic.200900008" @default.
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