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- W2026065199 abstract "The pyrolysis of C6F5I has been studied by the toluene carrier method over the temperature range of 900–978°K with contact times of 0.4–2.0 seconds and total pressures of 11.2–19.5 torr. Percent decomposition ranged from 8.6 to 97.7%. With toluene-to-C6F5I molar ratios of greater than 150, 85–100% of the C6F5 released abstracts a hydrogen atom from toluene to produce C6F5H. No significant quantities of I2 were observed and the only major gaseous product was HI. Within the limits of the experimental method the decomposition of C6F5I was first order and homogeneous. Least squares analysis of log k1 and 103/T(C6F5I → C6F5 + I) values gives while a weighted line of best fit yields. Based on this latter equation D[C6F5I] at 298°K is estimated as 66.2 kcal/mole." @default.
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- W2026065199 date "1974-03-01" @default.
- W2026065199 modified "2023-10-12" @default.
- W2026065199 title "Determination ofD[C6F5-I] by the toluene carrier method" @default.
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- W2026065199 doi "https://doi.org/10.1002/kin.550060205" @default.
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