Matches in SemOpenAlex for { <https://semopenalex.org/work/W2026075950> ?p ?o ?g. }
- W2026075950 endingPage "484" @default.
- W2026075950 startingPage "472" @default.
- W2026075950 abstract "In the preparation of nanocomposites, there is competition between the dispersion of nanoparticles and the formation of agglomerates. In this study, radical copolymerization of ethyl acrylate and methyl methacrylate initiated by 2,2‐azobis (isobutyro) nitrile (AIBN) was performed, in the presence of titanium oxide (TiO2) nanoparticles modified in a new approach; a good dispersion of the nanoparticles in the unsaturated polyester (UP) matrix was obtained. The TiO2 nanoparticles were exposed to 3‐(methacryloxy) propyl trimethoxy silane as the coupling agent. The presence of coupling agent‐grafted TiO2 nanoparticles in the copolymerization process resulted in the formation of a polymeric layer on the surface of the TiO2 nanoparticles (doubly modified‐TiO2). The grafting of coupling agent molecules and consequently copolymer macromolecular chains onto the surface of TiO2 nanoparticles was investigated using Fourier transform infrared (FTIR) analysis. It found that the formation of an acrylate layer on the surface of nanoparticles was successful. Then, unsaturated polyester (UP)/TiO2 nanocomposites were prepared. The morphology was studied using transmission electron microscopy (TEM). Mechanical properties and ultraviolet visible (UV/VIS) spectroscopy of various samples, including the doubly modified‐TiO2 nanoparticles, with different nanoparticle inclusions and the unmodified‐TiO2 nanoparticles, were also investigated. The results showed the doubly modified‐TiO2 nanoparticles, compared to those of unmodified‐TiO2, had better nanoparticle dispersion causing improvement in the mechanical properties and UV shielding." @default.
- W2026075950 created "2016-06-24" @default.
- W2026075950 creator A5008538443 @default.
- W2026075950 creator A5021876549 @default.
- W2026075950 creator A5024049517 @default.
- W2026075950 creator A5058142310 @default.
- W2026075950 date "2008-04-01" @default.
- W2026075950 modified "2023-10-15" @default.
- W2026075950 title "In situ Radical Copolymerization in Presence of Surface‐Modified TiO2 Nanoparticles: Influence of a Double Modification on Properties of Unsaturated Polyester (UP) Nanocomposites" @default.
- W2026075950 cites W1977115476 @default.
- W2026075950 cites W1982985313 @default.
- W2026075950 cites W1988884689 @default.
- W2026075950 cites W1989432462 @default.
- W2026075950 cites W1998754560 @default.
- W2026075950 cites W2002600092 @default.
- W2026075950 cites W2006060524 @default.
- W2026075950 cites W2007497419 @default.
- W2026075950 cites W2011296001 @default.
- W2026075950 cites W2018705326 @default.
- W2026075950 cites W2019363217 @default.
- W2026075950 cites W2019916184 @default.
- W2026075950 cites W2022692523 @default.
- W2026075950 cites W2024319768 @default.
- W2026075950 cites W2025669689 @default.
- W2026075950 cites W2029775829 @default.
- W2026075950 cites W2030697794 @default.
- W2026075950 cites W2033170887 @default.
- W2026075950 cites W2042661461 @default.
- W2026075950 cites W2049793376 @default.
- W2026075950 cites W2051428365 @default.
- W2026075950 cites W2058322375 @default.
- W2026075950 cites W2063315631 @default.
- W2026075950 cites W2064976128 @default.
- W2026075950 cites W2067227488 @default.
- W2026075950 cites W2067918294 @default.
- W2026075950 cites W2067970426 @default.
- W2026075950 cites W2084438377 @default.
- W2026075950 cites W2087122360 @default.
- W2026075950 cites W2089498333 @default.
- W2026075950 cites W2093681230 @default.
- W2026075950 cites W2103570394 @default.
- W2026075950 cites W2117024166 @default.
- W2026075950 cites W2119291797 @default.
- W2026075950 cites W2120392853 @default.
- W2026075950 cites W2142001117 @default.
- W2026075950 cites W2153135279 @default.
- W2026075950 cites W2164376066 @default.
- W2026075950 cites W4234728223 @default.
- W2026075950 doi "https://doi.org/10.1080/00222340801955065" @default.
- W2026075950 hasPublicationYear "2008" @default.
- W2026075950 type Work @default.
- W2026075950 sameAs 2026075950 @default.
- W2026075950 citedByCount "10" @default.
- W2026075950 countsByYear W20260759502013 @default.
- W2026075950 countsByYear W20260759502014 @default.
- W2026075950 countsByYear W20260759502015 @default.
- W2026075950 countsByYear W20260759502017 @default.
- W2026075950 countsByYear W20260759502018 @default.
- W2026075950 countsByYear W20260759502020 @default.
- W2026075950 crossrefType "journal-article" @default.
- W2026075950 hasAuthorship W2026075950A5008538443 @default.
- W2026075950 hasAuthorship W2026075950A5021876549 @default.
- W2026075950 hasAuthorship W2026075950A5024049517 @default.
- W2026075950 hasAuthorship W2026075950A5058142310 @default.
- W2026075950 hasConcept C115537861 @default.
- W2026075950 hasConcept C127413603 @default.
- W2026075950 hasConcept C155672457 @default.
- W2026075950 hasConcept C15920480 @default.
- W2026075950 hasConcept C159985019 @default.
- W2026075950 hasConcept C160892712 @default.
- W2026075950 hasConcept C171250308 @default.
- W2026075950 hasConcept C188027245 @default.
- W2026075950 hasConcept C192562407 @default.
- W2026075950 hasConcept C2779989194 @default.
- W2026075950 hasConcept C42360764 @default.
- W2026075950 hasConcept C521977710 @default.
- W2026075950 hasConcept C92880739 @default.
- W2026075950 hasConceptScore W2026075950C115537861 @default.
- W2026075950 hasConceptScore W2026075950C127413603 @default.
- W2026075950 hasConceptScore W2026075950C155672457 @default.
- W2026075950 hasConceptScore W2026075950C15920480 @default.
- W2026075950 hasConceptScore W2026075950C159985019 @default.
- W2026075950 hasConceptScore W2026075950C160892712 @default.
- W2026075950 hasConceptScore W2026075950C171250308 @default.
- W2026075950 hasConceptScore W2026075950C188027245 @default.
- W2026075950 hasConceptScore W2026075950C192562407 @default.
- W2026075950 hasConceptScore W2026075950C2779989194 @default.
- W2026075950 hasConceptScore W2026075950C42360764 @default.
- W2026075950 hasConceptScore W2026075950C521977710 @default.
- W2026075950 hasConceptScore W2026075950C92880739 @default.
- W2026075950 hasIssue "3" @default.
- W2026075950 hasLocation W20260759501 @default.
- W2026075950 hasOpenAccess W2026075950 @default.
- W2026075950 hasPrimaryLocation W20260759501 @default.
- W2026075950 hasRelatedWork W1519473 @default.
- W2026075950 hasRelatedWork W1983138719 @default.
- W2026075950 hasRelatedWork W1998361848 @default.
- W2026075950 hasRelatedWork W2032087176 @default.