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- W2026081084 abstract "The broadline NMR spectra of H2O and D2O absorbed in parallel fibers of highly crystalline rayon have been found to consist of two lines, whose separation depends upon the angle between the fiber axis and the magnetic field. The D2O splitting, resulting from quadrupole perturbation of the nuclear Zeeman levels, was about 10 times greater than the H2O splitting, produced by direct nuclear dipole-dipole interaction. Two models for the partial orientation of water molecules are discussed, (I) in which the molecules rotate about a fixed axis, and (II) in which the molecules reorient rapidly about all possible axes, but maintain a small resultant projection, along the fiber axis. Model I is shown to be incorrect for the rayon fibers, on the basis of the combined H2O and D2O results; Model II, however, appears to be applicable not only to rayon but to other examples of partially oriented water as well." @default.
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- W2026081084 date "1968-01-15" @default.
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- W2026081084 title "Broadline NMR Study of H2O and D2O in Oriented Rayon Fibers" @default.
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- W2026081084 doi "https://doi.org/10.1063/1.1668719" @default.
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