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• W2026091566 abstract "Describes a series of experiments designed to investigate the factors which limit the maximum resolution obtainable with a conventional quadrupole mass spectrometer under normal operating conditions. Included in the investigation were the effects of imperfections in mechanical construction and electrical supplies and also operation with contaminated electrode surfaces. In normal operation and with reasonable care taken in the mechanical construction and assembly, the finite length of the quadrupole rods, in this case 150 mm, was the principle factor setting an upper limit to the resolution. All the results suggested that the ions did not spend a sufficient time in the quadrupole to reach an equilibrium oscillation in the transverse AC field. Under all operating conditions resolution was found to be dependent, to a first approximation, on the number of cycles of AC field N experienced by the ions. The dependence of maximum resolution Rm on N was found to follow the simple empirical relationship, Rm=KN1.7. This formula applied for both low and high energy ions (2-32 eV) and for the mass range H2+ to Xe+." @default.
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• W2026091566 date "1972-05-01" @default.
• W2026091566 modified "2023-10-18" @default.
• W2026091566 title "An investigation of the factors determining maximum resolution in a quadrupole mass spectrometer" @default.
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• W2026091566 doi "https://doi.org/10.1088/0022-3735/5/5/016" @default.
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