Matches in SemOpenAlex for { <https://semopenalex.org/work/W2026100157> ?p ?o ?g. }
Showing items 1 to 95 of
95
with 100 items per page.
- W2026100157 endingPage "238" @default.
- W2026100157 startingPage "225" @default.
- W2026100157 abstract "We have observed and assigned the rotational spectra of 18O-glycine and, for the amino and hydroxy groups, all monodeutero and dideutero isotopically substituted species of the conformer of glycine which has the most intense microwave spectrum, gly(2). The derived spectroscopic data made possible the first complete gas-phase structural determination of an aminoacid. The values for the molecular parameters determined in a least-squares fit are well resolved and in harmony with the results for similar molecules and the predictions of high-level ab initio calculations. Calculation of the ab initio potential energy function for the amino torsion at the MP2/6-31G∗∗ level confirms that a large-amplitude vibrational motion is associated with the gly(2) species. It was found that the standard deviations in the results from the least-squares fit of the molecular parameters of both gly(2) were anomalously large. A similar effect was found in a test molecule—formamide. We conclude that when the experimentally derived rotational constants for a molecule are vibrationally averaged over a large-amplitude motion the explicit inclusion of LAM rotation–vibration interaction appears necessary to achieve more precise results." @default.
- W2026100157 created "2016-06-24" @default.
- W2026100157 creator A5005463847 @default.
- W2026100157 creator A5024414057 @default.
- W2026100157 creator A5074625141 @default.
- W2026100157 creator A5080820060 @default.
- W2026100157 date "1999-08-01" @default.
- W2026100157 modified "2023-10-18" @default.
- W2026100157 title "Molecular structure of a conformer of glycine by microwave spectroscopy" @default.
- W2026100157 cites W1964909967 @default.
- W2026100157 cites W1969879876 @default.
- W2026100157 cites W1971659155 @default.
- W2026100157 cites W1978076087 @default.
- W2026100157 cites W1981618328 @default.
- W2026100157 cites W1982859863 @default.
- W2026100157 cites W1999496551 @default.
- W2026100157 cites W2000129724 @default.
- W2026100157 cites W2004070888 @default.
- W2026100157 cites W2006460264 @default.
- W2026100157 cites W2016023215 @default.
- W2026100157 cites W2016925395 @default.
- W2026100157 cites W2026135109 @default.
- W2026100157 cites W2029123995 @default.
- W2026100157 cites W2053539209 @default.
- W2026100157 cites W2054966361 @default.
- W2026100157 cites W2055543120 @default.
- W2026100157 cites W2063429481 @default.
- W2026100157 cites W2089773530 @default.
- W2026100157 cites W2093643428 @default.
- W2026100157 cites W2094097494 @default.
- W2026100157 cites W2094676288 @default.
- W2026100157 cites W2148151498 @default.
- W2026100157 cites W2950582174 @default.
- W2026100157 cites W3004797146 @default.
- W2026100157 cites W3024290514 @default.
- W2026100157 cites W4240873916 @default.
- W2026100157 doi "https://doi.org/10.1016/s0022-2860(99)00181-7" @default.
- W2026100157 hasPublicationYear "1999" @default.
- W2026100157 type Work @default.
- W2026100157 sameAs 2026100157 @default.
- W2026100157 citedByCount "67" @default.
- W2026100157 countsByYear W20261001572012 @default.
- W2026100157 countsByYear W20261001572013 @default.
- W2026100157 countsByYear W20261001572014 @default.
- W2026100157 countsByYear W20261001572015 @default.
- W2026100157 countsByYear W20261001572016 @default.
- W2026100157 countsByYear W20261001572018 @default.
- W2026100157 countsByYear W20261001572019 @default.
- W2026100157 countsByYear W20261001572020 @default.
- W2026100157 countsByYear W20261001572022 @default.
- W2026100157 crossrefType "journal-article" @default.
- W2026100157 hasAuthorship W2026100157A5005463847 @default.
- W2026100157 hasAuthorship W2026100157A5024414057 @default.
- W2026100157 hasAuthorship W2026100157A5074625141 @default.
- W2026100157 hasAuthorship W2026100157A5080820060 @default.
- W2026100157 hasConcept C147597530 @default.
- W2026100157 hasConcept C178790620 @default.
- W2026100157 hasConcept C183971685 @default.
- W2026100157 hasConcept C185592680 @default.
- W2026100157 hasConcept C18705241 @default.
- W2026100157 hasConcept C2778270854 @default.
- W2026100157 hasConcept C2781442258 @default.
- W2026100157 hasConcept C31100168 @default.
- W2026100157 hasConcept C32909587 @default.
- W2026100157 hasConcept C41999313 @default.
- W2026100157 hasConceptScore W2026100157C147597530 @default.
- W2026100157 hasConceptScore W2026100157C178790620 @default.
- W2026100157 hasConceptScore W2026100157C183971685 @default.
- W2026100157 hasConceptScore W2026100157C185592680 @default.
- W2026100157 hasConceptScore W2026100157C18705241 @default.
- W2026100157 hasConceptScore W2026100157C2778270854 @default.
- W2026100157 hasConceptScore W2026100157C2781442258 @default.
- W2026100157 hasConceptScore W2026100157C31100168 @default.
- W2026100157 hasConceptScore W2026100157C32909587 @default.
- W2026100157 hasConceptScore W2026100157C41999313 @default.
- W2026100157 hasLocation W20261001571 @default.
- W2026100157 hasOpenAccess W2026100157 @default.
- W2026100157 hasPrimaryLocation W20261001571 @default.
- W2026100157 hasRelatedWork W1967729169 @default.
- W2026100157 hasRelatedWork W2005449902 @default.
- W2026100157 hasRelatedWork W2016427059 @default.
- W2026100157 hasRelatedWork W2020404857 @default.
- W2026100157 hasRelatedWork W2047633009 @default.
- W2026100157 hasRelatedWork W2053800933 @default.
- W2026100157 hasRelatedWork W2075617427 @default.
- W2026100157 hasRelatedWork W2082287996 @default.
- W2026100157 hasRelatedWork W2092652216 @default.
- W2026100157 hasRelatedWork W2171500806 @default.
- W2026100157 hasVolume "485-486" @default.
- W2026100157 isParatext "false" @default.
- W2026100157 isRetracted "false" @default.
- W2026100157 magId "2026100157" @default.
- W2026100157 workType "article" @default.