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- W2026102622 abstract "The conductivity of poly(3-dodecylthiophene), which decreases after a heating-cooling cycle, again increases to the original value in a period of several days, while ESR and the optical properties showed no marked relaxation phenomenon. The crystal structure of poly(3-dodecylthiophene) studied by X-ray diffraction measurements also showed marked changes in its lattice parameters a and b in the same period after the heat treatment. Relaxation to the original smaller b-value which corresponds to twice the distance between the neighbouring two conjugation planes was observed after the heat treatment. This is regarded as the origin of the relaxation in the conductivity. Thus, the increase in conductivity during the relaxation is interpreted in terms of the increase in the probability of inter-chain hopping of charge carriers and therefore carrier mobility with decreasing lattice parameter b. Conformational relaxation from gauche type to trans type was also observed in an FTIR analysis of the side alkyl chains." @default.
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- W2026102622 date "1994-05-30" @default.
- W2026102622 modified "2023-09-24" @default.
- W2026102622 title "Thermal relaxation in the electrical conductivity and structure of poly(3-dodecylthiophene)" @default.
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- W2026102622 doi "https://doi.org/10.1088/0953-8984/6/22/002" @default.
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