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- W2026105870 abstract "EPR studies on two types of nanoparticles of Fe3+ doped, 0.1–10%, ZnO, NL and QJ, prepared using similar chemical hydrolysis methods, in diethylene glycol, and in denatured ethanol solutions, respectively, were carried out at X-band (~9.5 GHz) at 77 K and at Q-band (~34.0 GHz) at 10, 80, and 295 K. To interpret the experimental results, EPR spectra were simulated by exact diagonalization of the spin-Hamiltonian matrix to identify the Fe ions at different magnetically active sites in these samples. The simulation for NL samples revealed that they contained (i) Fe3+ ions, which substituted for Zn ions, the zero-field splitting (ZFS) parameter which has a large distribution over the sample due to oxygen vacancies in the second coordination sphere; (ii) EPR signal from surface oxygen defects; and (iii) ferromagnetically (FM) coupled Fe ions with concentration of Fe more than 1%. The EPR spectra for QJ samples are very different from those for NL samples, exhibiting only rather intense FM EPR lines. The FM and EPR spectra in NL and/or QJ samples are found to vary strongly with differences in the surface morphology of nanoparticles." @default.
- W2026105870 created "2016-06-24" @default.
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- W2026105870 date "2014-08-01" @default.
- W2026105870 modified "2023-09-27" @default.
- W2026105870 title "An X- and Q-band Fe3+ EPR study of nanoparticles of magnetic semiconductor Zn1−Fe O" @default.
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- W2026105870 doi "https://doi.org/10.1016/j.jmmm.2014.03.031" @default.
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