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- W2026112999 abstract "Small vibration shifts of usually 10 to 50 cm—1 can be observed superimposed on the electronic shifts of 200 to 1000 cm—1 which occur on solvation of aromatic polynuclear hydrocarbons. Vibration assignments for benzene indicate that the observed behavior of its vibration bands is due to the perturbation of a single vibration in the electronically excited benzene molecule. The change corresponds to an increase of frequency for the excited state Eg+3080-cm—1 C–H vibration. A similar phenomenon can be detected in the naphthalene spectrum. The results are compared to the recent work of Fishman, Benson, Wiederkehr, and Drickamer on pressure perturbations of vibrations in electronic ground state molecules in solution." @default.
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- W2026112999 date "1959-06-01" @default.
- W2026112999 modified "2023-09-25" @default.
- W2026112999 title "Vibration Perturbations in Electronically Excited Molecules" @default.
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- W2026112999 doi "https://doi.org/10.1063/1.1730213" @default.
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