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- W2026163919 abstract "Solvolysis of delphisine in refluxing methanol gives 8-deacetyl-8-O-methyl-1-epi-delphisine. Similarly, hydrolysis of delphisine in boiling water affords 14-O-acetyl-1-epi-neoline and solvolysis of 8-O-acetylneoline in methanol gives 8-O-methyl-1-epi-neoline. The structures of the products have been proved by spectral data and comparison with authentic samples. For epimerization to occur, both a α-OH-1 and a OAc-8 group are necessary. Mechanisms for the epimerization are discussed." @default.
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- W2026163919 date "1990-01-01" @default.
- W2026163919 modified "2023-09-29" @default.
- W2026163919 title "An unusual epimerization of the α-OH-1 group of the norditerpenoid alkaloid delphisine" @default.
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- W2026163919 doi "https://doi.org/10.1016/0031-9422(90)85293-o" @default.
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