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• W2026171460 endingPage "202" @default.
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• W2026171460 abstract "Heat capacity of the halogen-bridged mixed-valence complex Pt2(dta)4I (dta = CH3CS2-) has been measured in the temperature region between 6 and 386 K. The complex exhibited a phase transition of order−disorder type at Ttrs = 373.4 K, from being arranged in an ordered helical form of four dta ligand planes around the central Pt−Pt axis to dynamically jumping between two orientations. Neither latent heat nor distinct thermal hysteresis was observed for the phase transition, suggesting that the phase transition is of higher-order rather than of first-order. The transition enthalpy and entropy were determined to be ΔtrsH = 1.91 ± 0.02 kJ mol-1 and ΔtrsS = 5.25 ± 0.07 J K-1 mol-1, respectively. The transition entropy close to R ln 2 (= 5.76 J K-1 mol-1), where R is the gas constant, implies that the twisting motion of the four dta ligands takes place in a synchronized way. No thermal anomaly was detected around 300 and 90 K, where a Mott transition from the one-dimensional metallic phase to the semiconducting phase and a spin-Peierls-like transition have been expected. The reason for the absence of these transitions in calorimetry is discussed briefly." @default.
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• W2026171460 date "2001-12-12" @default.
• W2026171460 modified "2023-09-27" @default.
• W2026171460 title "Heat Capacity of the Halogen-Bridged Mixed-Valence Complex Pt₂(dta)₄I (dta = CH₃CS₂^-)" @default.
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• W2026171460 doi "https://doi.org/10.1021/jp013038m" @default.
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