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- W2026171616 abstract "As is the case with their polycrystalline counterparts, the diagenetic stabilization of monocrystalline rock-forming carbonate skeletons which consist of the metastable calcium carbonate phase, Mg-calcite, is controlled by the process of dissolution and reprecipitation. In this study, the meteoric diagenesis of echinoderm skeletal parts — single crystals consisting of Mg-calcite — is examined experimentally. Experiments simulating as much as possible natural meteoric vadose conditions were performed and the properties of the products were compared with those of the starting materials using standard analytical procedures. By far the most informative results were yielded by scanning electron microscopy. It is found that in monocrystalline skeletons such as echinoderms the monocrystals are preserved during diagenesis, despite the necessarily destructive dissolution-reprecipitation process. In addition, overgrowths on the precursor monocrystal skeletal grains are epitaxial, inheriting crystallographic information from their precursors. It is known that carbonate crystals undergoing dissolution diagenesis do so not only over geologically long periods of time, but also in most cases do so piecewise, slowly and on the ultra-scale. In this way portions of it are always available to serve as seed for the epitaxial growth of calcite. Once single-crystal growth is seeded, provided growth rate, solution super-saturation and temperature are low enough to discourage spontaneous nucleation, the material will continue to grow as a single crystal." @default.
- W2026171616 created "2016-06-24" @default.
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- W2026171616 date "1989-09-01" @default.
- W2026171616 modified "2023-10-04" @default.
- W2026171616 title "Diagenetic transformation of magnesium calcite in a monocrystalline rock-forming carbonate skeleton of an echinoderm" @default.
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- W2026171616 doi "https://doi.org/10.1016/0009-2541(89)90098-3" @default.
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