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- W2026177353 abstract "Series of 123- and 2212-type crystals were grown from non-stoichiometric melts and were investigated by electron-probe microanalysis (EPMA), X-ray diffraction (XRD) and optical methods. Among doped 123-type crystals, a group of samples has been distinguished with ordered distribution of cations. The presence of impurities in Cu(1) sites and large rare-earth (RE) cations has been determined to cause the structure ordering. The 123-type crystals with random and ordered cation distribution correspond to two regions of superconductivity, when they are scaled with respect to deficiency of Cu sites. In the BiPbSrCa, Y, RECuO system, series of solid solutions have been distinguished in which chemical composition, lattice parameters and properties change continuously. An increase of carrier concentration at intergrowth of two isostructural phases and the presence of regions with large deviation from stoichiometry are discussed." @default.
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- W2026177353 date "1996-09-01" @default.
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- W2026177353 title "Influence of the cation sublattice on the growth, structure and properties of single crystals of 123- and 2212-type high-Tc superconductors" @default.
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- W2026177353 doi "https://doi.org/10.1016/0022-0248(96)00098-x" @default.
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