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• W2026221179 endingPage "1235" @default.
• W2026221179 startingPage "1229" @default.
• W2026221179 abstract "Abstract The nanoscopic structure of thermoresponsive dendronized polymers below the critical aggregation temperature ( T C ) is revealed by CW EPR spectroscopy. At temperatures far below T C , the water‐swollen polymers start to dehydrate and hydrophobic cavities are formed. Two different dehydration processes can be discerned, the more effective of which is observed within 4 K below T C . The dehydration predominantly takes place at the peripheral dendritic shell, rendering it increasingly hydrophobic and eventually triggering an interchain aggregation and the formation of mesoglobules at the critical temperature. While the polymer aggregation is mainly dependent on the dendron periphery, the efficiency of the dehydration below T C is closely related to the hydrophobicity of the dendritic core. magnified image" @default.
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• W2026221179 date "2011-04-13" @default.
• W2026221179 modified "2023-10-18" @default.
• W2026221179 title "EPR Spectroscopy Provides a Molecular View on Thermoresponsive Dendronized Polymers Below the Critical Temperature" @default.
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• W2026221179 doi "https://doi.org/10.1002/macp.201100022" @default.
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