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- W2026233800 abstract "The behavior of neptunium(VI), -(V) and -(IV) in carbonate-bicarbonate buffers (1 M) has been examined electrochemically and spectroscopically. Np(VI) undergoes a one-electron quasi-reversible reduction to Np(V) at +0.22 V vs SSCE Np(V) is reduced irreversibly to Np(IV) at ca. −1.8 V. Although Np(V) is readily oxidized to Np(VI), no oxidation of Np(IV) was observed. Spectroscopic results indicate that the Np(VI)-(V) reaction involves one reactant and one product. The spectrum of Np(IV) in 1 M carbonate-bicarbonate has been quantitatively analyzed. Comparisons to results for uranium under similar conditions are presented." @default.
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- W2026233800 title "Electrochemical and spectroscopic studies of neptunium(VI), -(V) and -(IV) in carbonate-bicarbonate buffers" @default.
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- W2026233800 doi "https://doi.org/10.1016/0022-1902(81)80643-4" @default.
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