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• W2026248166 abstract "The influence of a number of factors, i.e. amine basicity, substrate structure, temperature and deuterium isotope effect, on the rate of phenyl β-bromoethyl sulphone and aryl β-chloroethyl sulphone 1,2-elimination by reaction with amines in acetonitrile was investigated. On the basis of a comparative analysis of the ρ0, β, kH/kD, ΔH‡ and ΔS values obtained with those for the reaction of β-halopropiophenone 1,2-elimination, the conclusion was drawn that the E2 mechanism with an anion-like transition state occurs for the given substrates under the conditions studied." @default.
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• W2026248166 date "1994-10-01" @default.
• W2026248166 modified "2023-09-23" @default.
• W2026248166 title "Kinetics and mechanism of the interaction of amines with aryl ?-haloethyl sulphones" @default.
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• W2026248166 doi "https://doi.org/10.1002/poc.610071002" @default.
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