FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2026256593> ?p ?o ?g. }

• W2026256593 endingPage "1894" @default.
• W2026256593 startingPage "1884" @default.
• W2026256593 abstract "An approximate analytical model of film formation by interfacial polycondensation is presented. The analysis requires knowledge of a minimal set of certain kinetic parameters (monomer diffusivities and reaction rate constants) and reaction conditions (monomer concentrations and thickness of the unstirred layer). The process proceeds as a succession of two or three markedly different kinetic regimes. Each regime (insipient film formation, slowdown, and diffusion-limited growth) sets a different pattern of local polymer accumulation, with important implications for the structure of the emerging film. At the incipient stage, a loose polymer film begins to emerge in a fixed narrow region inside the boundary layer, followed by gradual densification of the middle part of the film. A condition for film formation is thus formulated on the basis of our analysis. The model predicts that two different scenarios are possible, which depend on the permeability of the polymer: films with a low permeability to both monomers pass through an abrupt slowdown of film growth, whereas permeable films undergo a smooth transition between the incipient film formation and diffusion-limited regimes. The model incorporates the highly important effects of the accumulation of reactive end groups and the decrease of monomer diffusion with the polymer concentration on the kinetics of the process and film characteristics. In addition, the validity of the utilized mean-field approach is analyzed, and the analysis suggests a direct correlation between the roughness and the thickness of the film. The results are in good agreement with an earlier numerical study and the direct structural studies of polyamide membrane films." @default.
• W2026256593 created "2016-06-24" @default.
• W2026256593 creator A5000571280 @default.
• W2026256593 date "2005-01-29" @default.
• W2026256593 modified "2023-10-14" @default.
• W2026256593 title "Kinetics of Film Formation by Interfacial Polycondensation" @default.
• W2026256593 cites W1974285276 @default.
• W2026256593 cites W1974843085 @default.
• W2026256593 cites W1977255921 @default.
• W2026256593 cites W1986962017 @default.
• W2026256593 cites W2003032882 @default.
• W2026256593 cites W2012330854 @default.
• W2026256593 cites W2013313790 @default.
• W2026256593 cites W2026753648 @default.
• W2026256593 cites W2037861204 @default.
• W2026256593 cites W2041341842 @default.
• W2026256593 cites W2043632580 @default.
• W2026256593 cites W2046785510 @default.
• W2026256593 cites W2048636247 @default.
• W2026256593 cites W2057111385 @default.
• W2026256593 cites W2063054674 @default.
• W2026256593 cites W2069047770 @default.
• W2026256593 cites W2070247566 @default.
• W2026256593 cites W2071067648 @default.
• W2026256593 cites W2078711544 @default.
• W2026256593 cites W2089717357 @default.
• W2026256593 cites W2093575289 @default.
• W2026256593 cites W2101834846 @default.
• W2026256593 cites W2103904302 @default.
• W2026256593 cites W2111243341 @default.
• W2026256593 cites W2111464588 @default.
• W2026256593 cites W2151124643 @default.
• W2026256593 doi "https://doi.org/10.1021/la048085v" @default.
• W2026256593 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/15723485" @default.
• W2026256593 hasPublicationYear "2005" @default.
• W2026256593 type Work @default.
• W2026256593 sameAs 2026256593 @default.
• W2026256593 citedByCount "364" @default.
• W2026256593 countsByYear W20262565932012 @default.
• W2026256593 countsByYear W20262565932013 @default.
• W2026256593 countsByYear W20262565932014 @default.
• W2026256593 countsByYear W20262565932015 @default.
• W2026256593 countsByYear W20262565932016 @default.
• W2026256593 countsByYear W20262565932017 @default.
• W2026256593 countsByYear W20262565932018 @default.
• W2026256593 countsByYear W20262565932019 @default.
• W2026256593 countsByYear W20262565932020 @default.
• W2026256593 countsByYear W20262565932021 @default.
• W2026256593 countsByYear W20262565932022 @default.
• W2026256593 countsByYear W20262565932023 @default.
• W2026256593 crossrefType "journal-article" @default.
• W2026256593 hasAuthorship W2026256593A5000571280 @default.
• W2026256593 hasConcept C120882062 @default.
• W2026256593 hasConcept C121332964 @default.
• W2026256593 hasConcept C127413603 @default.
• W2026256593 hasConcept C148898269 @default.
• W2026256593 hasConcept C159467904 @default.
• W2026256593 hasConcept C159985019 @default.
• W2026256593 hasConcept C166940927 @default.
• W2026256593 hasConcept C17744445 @default.
• W2026256593 hasConcept C185592680 @default.
• W2026256593 hasConcept C188027245 @default.
• W2026256593 hasConcept C190399342 @default.
• W2026256593 hasConcept C192562407 @default.
• W2026256593 hasConcept C199539241 @default.
• W2026256593 hasConcept C2777242750 @default.
• W2026256593 hasConcept C41625074 @default.
• W2026256593 hasConcept C42360764 @default.
• W2026256593 hasConcept C521977710 @default.
• W2026256593 hasConcept C53033327 @default.
• W2026256593 hasConcept C55493867 @default.
• W2026256593 hasConcept C62520636 @default.
• W2026256593 hasConcept C69357855 @default.
• W2026256593 hasConcept C97355855 @default.
• W2026256593 hasConceptScore W2026256593C120882062 @default.
• W2026256593 hasConceptScore W2026256593C121332964 @default.
• W2026256593 hasConceptScore W2026256593C127413603 @default.
• W2026256593 hasConceptScore W2026256593C148898269 @default.
• W2026256593 hasConceptScore W2026256593C159467904 @default.
• W2026256593 hasConceptScore W2026256593C159985019 @default.
• W2026256593 hasConceptScore W2026256593C166940927 @default.
• W2026256593 hasConceptScore W2026256593C17744445 @default.
• W2026256593 hasConceptScore W2026256593C185592680 @default.
• W2026256593 hasConceptScore W2026256593C188027245 @default.
• W2026256593 hasConceptScore W2026256593C190399342 @default.
• W2026256593 hasConceptScore W2026256593C192562407 @default.
• W2026256593 hasConceptScore W2026256593C199539241 @default.
• W2026256593 hasConceptScore W2026256593C2777242750 @default.
• W2026256593 hasConceptScore W2026256593C41625074 @default.
• W2026256593 hasConceptScore W2026256593C42360764 @default.
• W2026256593 hasConceptScore W2026256593C521977710 @default.
• W2026256593 hasConceptScore W2026256593C53033327 @default.
• W2026256593 hasConceptScore W2026256593C55493867 @default.
• W2026256593 hasConceptScore W2026256593C62520636 @default.
• W2026256593 hasConceptScore W2026256593C69357855 @default.
• W2026256593 hasConceptScore W2026256593C97355855 @default.
• W2026256593 hasIssue "5" @default.
• W2026256593 hasLocation W20262565931 @default.

• next