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• W2026284490 endingPage "1230" @default.
• W2026284490 startingPage "1220" @default.
• W2026284490 abstract "A series of tricarbonyl rhenium(I) complexes of the type fac-[ReI(CO)3(ppl)(L)]0/+, where ppl is pyrazino[2,3-f][1,10]phenanthroline, and where L is Cl−, TfO−, 4-(tert-butyl)pyridine (tBu-py), 4-methoxypyridine (MeO-py), 4,4′-bipyridyl (bpy), or 10-(picolin-4-yl)phenothiazine (pptz), were synthesized and fully characterized. In all complexes, an increment in the electron-acceptor properties of ppl compared to the free ligand was observed. This effect was more significant for pyridine-type ligands, especially for pptz, compared to Cl− or TfO−. The properties of fac-[Re(CO)3(ppl)(pptz)]PF6 were compared with those of the analogous compound fac-[Re(CO)3(dppz)(pptz)]PF6, where dppz is dipyrido(3,2-a : 2′,3′-c)phenazine, the goal being to generate long-lived excited charge-transfer (CT) states. In this respect, fac-[Re(CO)3(ppl)(pptz)]PF6 seems to be a promising candidate." @default.
• W2026284490 created "2016-06-24" @default.
• W2026284490 creator A5006557383 @default.
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• W2026284490 date "2006-06-01" @default.
• W2026284490 modified "2023-10-16" @default.
• W2026284490 title "Synthesis and Characterization of Polypiridine-Based Rhenium(I) Complexes with Pyrazino[2,3-f][1,10]phenanthroline" @default.
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• W2026284490 doi "https://doi.org/10.1002/hlca.200690119" @default.
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