FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2026294545> ?p ?o ?g. }

• W2026294545 endingPage "3816" @default.
• W2026294545 startingPage "3812" @default.
• W2026294545 abstract "Abstract Addition of nitrosobenzene to β‐diketiminato and tris(pyrazolyl)borate copper complexes [[Me 2 NN F6 ]Cu(NCMe)] ( 2 ) and [ i Pr2 TpCu(NCMe)] ( 3 ) gives the corresponding nitrosobenzene adducts [[Me 2 NN F6 ]Cu(η 2 ‐ONPh)] ( 5 ) and [ i Pr2 TpCu{κ 1 ‐N(O)Ph}] ( 6 ). Backbonding to the nitrosoarene is strongest via the η 2 ‐ON binding mode, which is sterically inaccessible for the tris(pyrazolyl)borate complexes. The strength of the interaction is judged by the N–O bond length, the ν NO stretching frequencies observed for 5 and 6 , as well as by the DFT LUMO energies of 5 ‐η 2 ‐ON, 5‐ κ 1 ‐N, 6 ‐κ 1 ‐N, which range from highest to lowest. Nitrosoarene complexes 5 and 6 are also produced upon reaction of [[Me 2 NN F6 ]Cu(NCMe)] ( 2 ) and [ i Pr2 TpCu(NCMe)] ( 3 ) with 2 equiv. N ‐phenylhydroxylamine (PhNHOH), though a considerable amount of the azoxybenzene PhN=N(O)Ph is observed along with 6 . The addition of slight excess of NO to 5 and 6 results in the formation of copper(II) diazeniumdiolates [[Me 2 NN F6 ]Cu(κ 2 ‐O 2 N 2 Ph)] ( 7 ) and [ i Pr2 TpCu(κ 2 ‐O 2 N 2 Ph)] ( 8 ), which exhibit square‐planar and square‐pyramidal geometries, respectively. These findings give insight into PhNO and PhHNOH reactivity at copper(I) and foreshadow possible transformations of considerably more reactive nitroxyl (HNO) and hydroxylamine (H 2 NOH) analogues." @default.
• W2026294545 created "2016-06-24" @default.
• W2026294545 creator A5005652436 @default.
• W2026294545 creator A5006837034 @default.
• W2026294545 creator A5039736717 @default.
• W2026294545 creator A5053843065 @default.
• W2026294545 date "2013-07-01" @default.
• W2026294545 modified "2023-09-24" @default.
• W2026294545 title "Copper <i>C</i> ‐Nitroso Compounds: Activation of Hydroxylamines and NO Reactivity" @default.
• W2026294545 cites W1488020481 @default.
• W2026294545 cites W1505873700 @default.
• W2026294545 cites W1964058023 @default.
• W2026294545 cites W1971959075 @default.
• W2026294545 cites W1972297823 @default.
• W2026294545 cites W1979567315 @default.
• W2026294545 cites W1981995525 @default.
• W2026294545 cites W1993601025 @default.
• W2026294545 cites W1995290582 @default.
• W2026294545 cites W2004641607 @default.
• W2026294545 cites W2006172842 @default.
• W2026294545 cites W2009257720 @default.
• W2026294545 cites W2023831198 @default.
• W2026294545 cites W2025325315 @default.
• W2026294545 cites W2028033168 @default.
• W2026294545 cites W2035632121 @default.
• W2026294545 cites W2043286086 @default.
• W2026294545 cites W2056197807 @default.
• W2026294545 cites W2058556055 @default.
• W2026294545 cites W2059191118 @default.
• W2026294545 cites W2066079817 @default.
• W2026294545 cites W2078353000 @default.
• W2026294545 cites W2087751141 @default.
• W2026294545 cites W2117797139 @default.
• W2026294545 cites W2121367250 @default.
• W2026294545 cites W2199166367 @default.
• W2026294545 cites W2315748211 @default.
• W2026294545 cites W2328286996 @default.
• W2026294545 cites W2951613255 @default.
• W2026294545 cites W3020079057 @default.
• W2026294545 cites W4238609056 @default.
• W2026294545 cites W1984018310 @default.
• W2026294545 doi "https://doi.org/10.1002/ejic.201300378" @default.
• W2026294545 hasPublicationYear "2013" @default.
• W2026294545 type Work @default.
• W2026294545 sameAs 2026294545 @default.
• W2026294545 citedByCount "20" @default.
• W2026294545 countsByYear W20262945452015 @default.
• W2026294545 countsByYear W20262945452016 @default.
• W2026294545 countsByYear W20262945452017 @default.
• W2026294545 countsByYear W20262945452018 @default.
• W2026294545 countsByYear W20262945452019 @default.
• W2026294545 countsByYear W20262945452020 @default.
• W2026294545 countsByYear W20262945452021 @default.
• W2026294545 countsByYear W20262945452022 @default.
• W2026294545 countsByYear W20262945452023 @default.
• W2026294545 crossrefType "journal-article" @default.
• W2026294545 hasAuthorship W2026294545A5005652436 @default.
• W2026294545 hasAuthorship W2026294545A5006837034 @default.
• W2026294545 hasAuthorship W2026294545A5039736717 @default.
• W2026294545 hasAuthorship W2026294545A5053843065 @default.
• W2026294545 hasConcept C108204754 @default.
• W2026294545 hasConcept C142724271 @default.
• W2026294545 hasConcept C155647269 @default.
• W2026294545 hasConcept C161790260 @default.
• W2026294545 hasConcept C178790620 @default.
• W2026294545 hasConcept C179104552 @default.
• W2026294545 hasConcept C185592680 @default.
• W2026294545 hasConcept C201194858 @default.
• W2026294545 hasConcept C204787440 @default.
• W2026294545 hasConcept C2775888733 @default.
• W2026294545 hasConcept C2775932965 @default.
• W2026294545 hasConcept C2775999725 @default.
• W2026294545 hasConcept C2776142628 @default.
• W2026294545 hasConcept C2776910235 @default.
• W2026294545 hasConcept C2778478478 @default.
• W2026294545 hasConcept C2778803632 @default.
• W2026294545 hasConcept C544778455 @default.
• W2026294545 hasConcept C71240020 @default.
• W2026294545 hasConcept C71924100 @default.
• W2026294545 hasConcept C75473681 @default.
• W2026294545 hasConceptScore W2026294545C108204754 @default.
• W2026294545 hasConceptScore W2026294545C142724271 @default.
• W2026294545 hasConceptScore W2026294545C155647269 @default.
• W2026294545 hasConceptScore W2026294545C161790260 @default.
• W2026294545 hasConceptScore W2026294545C178790620 @default.
• W2026294545 hasConceptScore W2026294545C179104552 @default.
• W2026294545 hasConceptScore W2026294545C185592680 @default.
• W2026294545 hasConceptScore W2026294545C201194858 @default.
• W2026294545 hasConceptScore W2026294545C204787440 @default.
• W2026294545 hasConceptScore W2026294545C2775888733 @default.
• W2026294545 hasConceptScore W2026294545C2775932965 @default.
• W2026294545 hasConceptScore W2026294545C2775999725 @default.
• W2026294545 hasConceptScore W2026294545C2776142628 @default.
• W2026294545 hasConceptScore W2026294545C2776910235 @default.
• W2026294545 hasConceptScore W2026294545C2778478478 @default.
• W2026294545 hasConceptScore W2026294545C2778803632 @default.
• W2026294545 hasConceptScore W2026294545C544778455 @default.
• W2026294545 hasConceptScore W2026294545C71240020 @default.

• next