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• W2026326345 abstract "The thermally stimulated discharge currents (TSDC) of crystalline poly(ethylene terephthalate) (PET-c) show two clearly differentiated relaxations, αc and ρc, which could result from the α and ρ relaxations of amorphous PET as a consequence of the crystallization process. The evolution of α and ρ relaxations of amorphous PET has been studied by the application of a method which we have called thermal stimulation by steps (TSS) and by isothermal crystallization of amorphous samples for different times. The ρ relaxation increases due to progressive nucleation and subsequent growth of the nuclei until a maximum value is reached; from then on until extinction ρ is mainly affected by growth. The α relaxation decreases progressively until its total extinction following the increase of restrictions. For a certain degree of crystallinity, by applying the TSS method, simultaneous occurrence of α, ρ, αc and ρc is achieved, which implies that αc and ρc do not proceed from α and ρ and, consequently, that their origin is different." @default.
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• W2026326345 date "1988-10-01" @default.
• W2026326345 modified "2023-10-14" @default.
• W2026326345 title "Cold crystallization effect on α and ρ amorphous poly(ethylene terephthalate) relaxations by thermally stimulated discharge currents" @default.
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• W2026326345 doi "https://doi.org/10.1016/0032-3861(88)90385-0" @default.
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