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- W2026329193 abstract "Polyethylene glycol (PEG) serves as a novel matrix in capillary electrophoresis. The purpose of this work was to explore some evidence for hydrogen-bonding complex formation between analytes and PEG in the separation system using benzoic acids as model analytes. An increase in the column temperature resulted in a significant decrease in the interaction between PEG and substituted benzoic acids with hydrogen-donating groups. Addition of urea suppressed the interaction. NMR spectra of phenol and salicyclic acid in the presence of PEG in C2HCl3 showed an obvious electrostatic interaction, probably a hydrogen-bonding interaction, between the hydroxyl protons of the analytes and PEG. These results strongly support the contention that hydrogen-bonding interaction between the polyether segments of PEG and the hydrogen-donating groups of analytes occurs in the separation systems. Some other minor interactions controlling the separation are also described." @default.
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- W2026329193 date "1995-09-01" @default.
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- W2026329193 title "Hydrogen-bonding interaction in capillary electrophoresis using polyether matrices" @default.
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- W2026329193 doi "https://doi.org/10.1016/0021-9673(95)00519-s" @default.
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