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- W2026352622 abstract "While the two N atoms of a pair of NH3 molecules do not interact attractively, the replacement of one H with a F atom results in a direct N⋯N noncovalent bond, with an interaction energy of 4 kcal/mol, nearly as strong as a NH⋯N H-bond. Cl or Br-substitution also leads to an attractive force between the two N atoms, although the XN⋯N geometry does not represent a true minimum on the potential energy surface. Trimethylation of the electron donor NH3 strengthens both the NH⋯N and XN⋯N bonds." @default.
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- W2026352622 date "2011-09-01" @default.
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- W2026352622 title "Can two trivalent N atoms engage in a direct N⋯N noncovalent interaction?" @default.
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- W2026352622 doi "https://doi.org/10.1016/j.cplett.2011.08.028" @default.
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