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- W2026366818 abstract "We have calculated the vibrational spectra of the umbrella (ν2), the symmetric (ν1), and the asymmetric (ν3) N–H stretch mode for ammonia clusters from n=3–18. The results are based on recent structure calculations and a molecular perturbation approach that includes the anharmonicities. Clusters with high symmetry exhibit few lines only and show the expected blue shifts for the umbrella and red shifts for the two N–H stretch modes. The calculated frequencies of the umbrella mode agree very well with experimental results for n=2–5 as far as the general shape is concerned, but overestimate the absolute shifts." @default.
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- W2026366818 date "2001-05-08" @default.
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- W2026366818 title "Vibrational spectra of ammonia clusters from n=3 to 18" @default.
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- W2026366818 doi "https://doi.org/10.1063/1.1365097" @default.
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