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• W2026371505 abstract "Organic peroxides are slightly stable substances that can self-decompose under favourable conditions. During storage there can be a loss of activity if the temperature is above the recommended storage temperature. At higher temperatures this decomposition is self-accelerating. Many peroxides, are extremely shock sensitive or unstable in pure form and are, therefore, only commercially available in diluted solution. In this work, the thermal stability of 44 compounds is evaluated. The method suggested here for predicting the self-accelerating decomposition temperature (SADT) is based on the numerical solution of the equations derived from the mass and energy balances coupled to a heuristics to recognise parameter sets that produce runaway." @default.
• W2026371505 created "2016-06-24" @default.
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• W2026371505 date "2001-02-01" @default.
• W2026371505 modified "2023-09-27" @default.
• W2026371505 title "Safe storage temperature of peroxide initiators: prediction of self-accelerated decomposition temperature based on a runaway heuristics" @default.
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• W2026371505 doi "https://doi.org/10.1016/s0009-2509(00)00370-5" @default.
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