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• W2026388966 abstract "Electronic structures of 5,10,15,20-zinctetraphenylporphyrin (ZnTPP)/metal (Au, Ag, Al, Mg) interfaces prepared in ultrahigh vacuum condition were investigated by ultraviolet photoelectron spectroscopy (UPS). We found that the electronic energy levels of ZnTPP align with the vacuum level of substrate metal with a constant energy shift of the vacuum levels across the interface. These findings cannot be explained by the concepts of Fermi level alignment nor vacuum level alignment. We also found that sample exposure to oxygen induces energy level shift in close relation with change of substrate work function at oxygen exposure. The relation between the observed electronic structure and the electric characteristics of porphyrin/metal interfaces in solar cell is also discussed." @default.
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• W2026388966 date "1995-12-01" @default.
• W2026388966 modified "2023-09-27" @default.
• W2026388966 title "The electronic structure and energy level alignment of porphyrin/metal interfaces studied by ultraviolet photoelectron spectroscopy" @default.
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• W2026388966 doi "https://doi.org/10.1016/0368-2048(95)02517-0" @default.
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