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- W2026396145 abstract "The conversion of methylcyclopentane and the deactivation by coke formation was studied on Pt/Al2O3 and Pt-Sn/Al2O3 catalysts. The coking inhibits the conversion in a nearly linear relationship, no distinct influence of tin on the amount of coke was observed. But with tin containing catalysts the benzene formation is increased and the hydrogenolytic splitting is decreased. The selfpoisoning by coke varies the selectivities in a significant way. A similar change of selectivity was observed with increasing tin content also indicating a certain poisoning by tin. Tin inhibits the hydrogenolysis according to an ensemble effect and retards the deactivation of the catalyst by modifying the coke deposition." @default.
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- W2026396145 date "1983-11-01" @default.
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- W2026396145 title "Deactivation of supported pt and pt-sn catalysts in the conversion of methylcyclopentane" @default.
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- W2026396145 doi "https://doi.org/10.1016/0166-9834(83)80077-3" @default.
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