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- W2026398630 abstract "The considerations necessary for the development of a complete theory of excimer formation in crystals are analysed. A simple model which incorporates exciton-generated lattice distortion into the travelling exciton is presented, a distortion type related to excimer formation defined and the role it plays in establishing a route for excimer formation discussed. The consequences of a large change in pair molecule separation in going from crystal to excimer are emphasised and possible competition with photodimerization as an alternative end result mentioned. Referring to experimental evidence for a travelling excimer in 9-cyanoanthracene, it is shown here that a strong exciton-phonon coupling term peculiar to this crystal would be favourable. Mechanisms suggested elsewhere for migration of excimer excitation in pyrene are discussed in terms of the ideas developed here." @default.
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- W2026398630 date "1984-01-01" @default.
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- W2026398630 title "Exciton-induced lattice distortion and excimer formation" @default.
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