Matches in SemOpenAlex for { <https://semopenalex.org/work/W2026403296> ?p ?o ?g. }
- W2026403296 endingPage "16673" @default.
- W2026403296 startingPage "16667" @default.
- W2026403296 abstract "New selenium−nitrogen species were produced by condensing the effluent from an argon/nitrogen/selenium microwave discharge onto a 12 K substrate. Nitrogen-15 and selenium-76 and −80 isotopic substitutions, photolysis, and annealing provided basis for identification of the new product absorptions in the infrared spectrum. A weak band at 951 cm-1 is assigned to SeN and the very strong 1019 cm-1 band to ν3 of NSe2 radical with a 146 ± 5° valence angle. A new 1570 cm-1 band in this system is due to the SeNO radical, and a 1771 cm-1 absorption, also made from Se2 and NO, is due to the (SeSe)(NO) complex. Higher-order SexNy (x > 1) species give rise to bands at 904, 736, 616, and 529 cm-1. The argon/selenium discharge in quartz has also produced the SiSe, SiSe2, and SeSiO species. Structure and frequency calculations using density functional theory support the matrix infrared identification of these new selenium molecular species. The most stable (NSe)2 structure is calculated to be the cis form analogous to (NO)2, but by contrast, (NSe)2 has a stronger NN bond and Se−Se bonding." @default.
- W2026403296 created "2016-06-24" @default.
- W2026403296 creator A5029634322 @default.
- W2026403296 creator A5056540916 @default.
- W2026403296 creator A5063887861 @default.
- W2026403296 creator A5084599664 @default.
- W2026403296 date "1996-01-01" @default.
- W2026403296 modified "2023-10-01" @default.
- W2026403296 title "Reactions of Selenium in a Quartz Discharge Tube. Infrared Spectra and Density Functional Theory Calculations of New Selenium−Nitrogen and Selenium−Silicon Species in Solid Argon" @default.
- W2026403296 cites W1523353147 @default.
- W2026403296 cites W187577752 @default.
- W2026403296 cites W1965929763 @default.
- W2026403296 cites W1973262868 @default.
- W2026403296 cites W1975708211 @default.
- W2026403296 cites W1982667173 @default.
- W2026403296 cites W1995103016 @default.
- W2026403296 cites W2004140148 @default.
- W2026403296 cites W2006677203 @default.
- W2026403296 cites W2007093100 @default.
- W2026403296 cites W2008152183 @default.
- W2026403296 cites W2008788457 @default.
- W2026403296 cites W2010050190 @default.
- W2026403296 cites W2011322193 @default.
- W2026403296 cites W2013571791 @default.
- W2026403296 cites W2015942342 @default.
- W2026403296 cites W2032836133 @default.
- W2026403296 cites W2041404702 @default.
- W2026403296 cites W2042902152 @default.
- W2026403296 cites W2050362659 @default.
- W2026403296 cites W2054432149 @default.
- W2026403296 cites W2063230425 @default.
- W2026403296 cites W2065295001 @default.
- W2026403296 cites W2069133878 @default.
- W2026403296 cites W2077587281 @default.
- W2026403296 cites W2086792545 @default.
- W2026403296 cites W2093468433 @default.
- W2026403296 cites W2094733114 @default.
- W2026403296 cites W2133524519 @default.
- W2026403296 cites W2137424084 @default.
- W2026403296 cites W2148284063 @default.
- W2026403296 cites W2166060552 @default.
- W2026403296 cites W2173417959 @default.
- W2026403296 cites W2323788984 @default.
- W2026403296 cites W2604518828 @default.
- W2026403296 cites W2739274932 @default.
- W2026403296 cites W2950733976 @default.
- W2026403296 cites W2951811709 @default.
- W2026403296 cites W2951995082 @default.
- W2026403296 cites W3136489793 @default.
- W2026403296 cites W3137686599 @default.
- W2026403296 cites W3139058681 @default.
- W2026403296 cites W4244956128 @default.
- W2026403296 doi "https://doi.org/10.1021/jp961288a" @default.
- W2026403296 hasPublicationYear "1996" @default.
- W2026403296 type Work @default.
- W2026403296 sameAs 2026403296 @default.
- W2026403296 citedByCount "9" @default.
- W2026403296 countsByYear W20264032962013 @default.
- W2026403296 countsByYear W20264032962014 @default.
- W2026403296 countsByYear W20264032962017 @default.
- W2026403296 countsByYear W20264032962020 @default.
- W2026403296 countsByYear W20264032962022 @default.
- W2026403296 crossrefType "journal-article" @default.
- W2026403296 hasAuthorship W2026403296A5029634322 @default.
- W2026403296 hasAuthorship W2026403296A5056540916 @default.
- W2026403296 hasAuthorship W2026403296A5063887861 @default.
- W2026403296 hasAuthorship W2026403296A5084599664 @default.
- W2026403296 hasConcept C113196181 @default.
- W2026403296 hasConcept C120665830 @default.
- W2026403296 hasConcept C121332964 @default.
- W2026403296 hasConcept C147597530 @default.
- W2026403296 hasConcept C151730666 @default.
- W2026403296 hasConcept C152365726 @default.
- W2026403296 hasConcept C153642686 @default.
- W2026403296 hasConcept C158355884 @default.
- W2026403296 hasConcept C159985019 @default.
- W2026403296 hasConcept C178790620 @default.
- W2026403296 hasConcept C185592680 @default.
- W2026403296 hasConcept C192562407 @default.
- W2026403296 hasConcept C2777855556 @default.
- W2026403296 hasConcept C2777896788 @default.
- W2026403296 hasConcept C2779870107 @default.
- W2026403296 hasConcept C537208039 @default.
- W2026403296 hasConcept C547737533 @default.
- W2026403296 hasConcept C553756173 @default.
- W2026403296 hasConcept C86803240 @default.
- W2026403296 hasConceptScore W2026403296C113196181 @default.
- W2026403296 hasConceptScore W2026403296C120665830 @default.
- W2026403296 hasConceptScore W2026403296C121332964 @default.
- W2026403296 hasConceptScore W2026403296C147597530 @default.
- W2026403296 hasConceptScore W2026403296C151730666 @default.
- W2026403296 hasConceptScore W2026403296C152365726 @default.
- W2026403296 hasConceptScore W2026403296C153642686 @default.
- W2026403296 hasConceptScore W2026403296C158355884 @default.
- W2026403296 hasConceptScore W2026403296C159985019 @default.
- W2026403296 hasConceptScore W2026403296C178790620 @default.
- W2026403296 hasConceptScore W2026403296C185592680 @default.
- W2026403296 hasConceptScore W2026403296C192562407 @default.